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RP-M324 Analyzer for "Direct" thermal analysis
of Sorbent Traps for monitoring Hg emissions from coal-fired
power plants
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RA-915+ with RP-M324 is designed for field on-site
or laboratory “Direct” testing of carbon tubes for
Sorbent Trap Monitoring of Hg emissions from coal fired power
plants. US EPA validated thermal decomposition is referenced in
appendices K part 75 of the Clean Air Mercury Rule. Atomic Absorption
technology is used for no sample preparation analysis. Analysis
time is less than 2 minutes per sample. No liquid chemicals or
gas required, no chemical waste is generated.
In addition to Sorbent Traps, analyzer could be used for "Direct"
testing of ash, coal, and Ontario Hydro method generated
liquid samples. Mercury Speciation is available.
Multi point calibration protocol conforms to EPA Performance Based
Criteria Method.
| RA-915+
with RP-M324 |
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A sorbent Trap tube is cut and sorbent is transferred onto a
quartz ladle. The ladle is inserted into the analyzer thermo catalytic
conversion chamber heated to 800°C wherein mercury is converted
from a bound state to the atomic state by thermal decomposition
in a two-section furnace.
This approach requires no preconcentration on gold eliminating
the associated problems. The use of multipath cell combined with
“dry” converter provides highest sensitivity with
no interferences from the sample matrix. Mercury measurements
take place in the heated cell zone of converter directly coupled
to spectrometer. High temperature (800C) and short residence time
prevents Mercury atoms from recombining with any “active”
species generated due to high temperature decomposition of sample
matrix. External pump is used to draw ambient air and purify it
for combustion. No cylinders of oxidizer or compressed gases required.
No "clean room" required. Easy to use, maintain and transport.
| Results of 3X3 Spiked
carbon tube assay analyzed by PR-M324 |
Sample
Identification |
Measured
Concentration (ng) |
Spike
Amount (ng) |
%
Recovery |
Average
% Recovery |
180 ng replicate
#1 |
188.2 |
180.0 |
104.6 |
103.6
|
180 ng replicate
#2 |
193.0 |
180.0 |
107.2 |
180 ng replicate
#3 |
178.2 |
180.0 |
99.0 |
1400 ng replicate
#1 |
1388.4 |
1400.0 |
99.2 |
94.6
|
1400 ng replicate
#2 |
1274.3 |
1400.0 |
91.0 |
1400 ng replicate
#3 |
1309.7 |
1400.0 |
93.6 |
3000 ng replicate
#1 |
3030.0 |
3000.0 |
101.0 |
99.0
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3000 ng replicate
#2 |
3010.0 |
3000.0 |
100.3 |
3000 ng replicate
#3 |
2870.0 |
3000.0 |
95.7 |
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| Technical specifications |
| Detection limits: |
10 - 100,000 ng
- mercury
10 ug/kg - 100 mg/kg - Hg concentration
in sorbent, ash, coal, liquid "Ontario Hydro"
impinger samples |
| Direct analysis (results
in 2 minutes) for "small" and "large"
US EPA Method 324 tubes |
| Calibration |
"Spike" your own tube
by "direct" depositing NIST standard on sorbent
Attachment RP-91 for "spiking" tubes with
Elemental Mercury by reducing NIST standard is available |
| Set-up or take-down
time |
less than one hour |
| Utilities |
220/110v/60Hz, 600Watt |
| Dimensions and weight |
2 Rolling Pelican cases, total
60 lb |
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